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Black Jack All-Weather Roof Cement, Asphalt Cement for Roofs, 6230, Professional Use-02/02/2015
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Roof CementStructure such as solid, liquid, aerosol etc.
Form: pasteDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20244161 East 7th. Avenue
Tampa FL 33605
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 008052-42-4 -- 30.0-40.0 -- -- -- -- 008052-41-3 -- 8.0-15.0 Xn -- -- -- -- 007732-18-5 -- 35.0-45.0 -- -- -- -- 000108-67-8 -- <1 Xi, N -- -- -- -- 000095-63-6 -- <1 Xn, Xi, N -- -- -- -- 009004-34-6 -- 2.0-6.0 -- -- -- -- 001302-78-9 -- 1.0-5.0 -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Asphalt
008052-42-4
232-490-930.0-40.0 No -- -- -- No No Stoddard solvent
008052-41-3
232-489-38.0-15.0 No H226, H304, H315, H372, H412 P102, P260, P262, P273, P301+P310, P331 No No Water
007732-18-5
231-791-235.0-45.0 No -- -- -- No No Mesitylene (1,3,5-Trimethylbenzene)
000108-67-8
203-604-4<1 No H226, H319, H335, H315, H304, H411 P210, P301+P310, P331, P303+P361+P353, P305+P351+P338, P362+P364, P405, P501 No No 1,2,4-Trimethylbenzene
000095-63-6
202-436-9<1 No H226, H332, H319, H335, H315, H411 P210, P243, P280, P261, P302+P352, P305+P351+P338, P273, P391 No No Wood flour
009004-34-6
232-674-92.0-6.0 No -- -- -- No No Bentonite
001302-78-9
215-108-51.0-5.0 No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H226 : Flammable liquid and vapourH304 : May be fatal if swallowed and enters airwaysH315 : Causes skin irritationH319 : Causes serious eye irritationH332 : Harmful if inhaledH335 : May cause respiratory irritationH372 : Causes damage to organsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effects
- P102 : Keep out of reach of childrenP210 : Keep away from heat/sparks/open flames/hot surfacesP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP262 : Do not get in eyes, on skin, or on clothingP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP331 : Do NOT induce vomitingP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :February 02, 2015 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING1 2 0 -
V.O.C Information
Volatile Organic Compounds g/L With Solvent : <250
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SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
Hazard Statements
Warning. Flammable liquid (paste) and Vapor. Contains Combustible Petroleum Distillates. Harmful or Fatal if swallowed. Keep away from heat, sparks, and open flame. Avoid prolonged breathing of vapor and use only in adequate ventilation. Repeated and prolonged overexposure to solvent vapor may cause brain and nervous system damage, respiratory tract irritation, dizziness, or loss of consciousness. May cause skin and eye irritation.
Precautionary Statements
General
None.
Prevention
Avoid breathing dust, fume, gas, mist, vapors and/or spray. Do not handle until all safety precautions have been read and understood. Keep away from flames and hot surfaces. No smoking. Use personal protective equipment as required. Keep out of reach of children.
Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF ON SKIN: Wash with plenty of soap and water.
IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
Storage
Store in a closed container. Store in a well‐ventilated place.
Disposal
Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Warning. Flammable liquid (paste) and Vapor. Contains Combustible Petroleum Distillates. Harmful or Fatal if swallowed. Keep away from heat, sparks, and open flame. Avoid prolonged breathing of vapor and use only in adequate ventilation. Repeated and prolonged overexposure to solvent vapor may cause brain and nervous system damage, respiratory tract irritation, dizziness, or loss of consciousness. May cause skin and eye irritation.
Potential Health Effects
Eye Contact: May cause irritation.
Skin Contact: May cause irritation.
Inhalation: May cause irritation. Excessive breathing of high vapor concentration can cause possible unconsciousness and even asphyxiation.
Ingestion: May be harmful or fatal if swallowed. -
Chronic health effects
From SDS:
Repeated and prolonged exposure to the skin may cause dermatitis. -
Carcinogenicity
IARC has concluded that the following chemicals in this product are carcinogenic to humans (Group 1): silica, quartz. ACGIH has designated the following chemicals in this product as suspected human carcinogens (A2): silica, quartz. NTP has listed the following chemicals in this product as known human carcinogens: silica, quartz. Risk of cancer depends on duration and level of exposure to this product as a dust or aerosol mist.This product contains petroleum asphalt. Petroleum asphalt is not listed as a carcinogen by OSHA or NTP. The National Institute of Occupational Safety and Health (NIOSH), has concluded that at higher temperatures roofing asphalt fumes are a potential occupational carcinogen. If this product is heated or comes in contact with heated material, avoid breathing fumes. This product may contain small amounts of polycyclic aromatic hydrocarbons (PAH’s) which are recognized carcinogens in humans and experimental animals. Mouse skin painting studies of roofing asphalt vapor concentrate have shown evidence of tumor formation associated with localized skin irritation in recent studies. Inhalation studies of high airborne concentrations of asphalt/bitumen fumes in rats and mice produced bronchitis, pneumonitis, and lung changes such as fibrosis and cell damage. -
Handling information
KEEP OUT OF THE REACH OF CHILDREN! Keep away from heat and ignition sources. No Smoking. Use only with adequate ventilation. Store in a well-ventilated place. Keep container tightly closed. Keep container/package tightly closed in a cool, well-ventilated place. no sparks and no smoking. Avoid contact with strong oxidizing agents and acids. -
Disposal information
Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. -
California Prop. 65 Warning
Asphalt and Asphalt Fumes may contain detectable amounts of chemicals known to the State of California to cause cancer or reproductive harm
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First Aid
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.Skin Contact: Wash with plenty of soap and water. If irritation develops and persists, get medical attention.Inhalation: Call a POISON CENTER or doctor/physician if you feel unwell. Move victim to fresh air. If breathing is difficult, give oxygen.Ingestion: If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person.
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